ChemInform Abstract: Synthesis and Properties of 1,2-Difluorodinitroethylene

Autor:	Thomas G. Archibald, Clifford George, D. Tzeng, Richard Gilardi, Kurt Baum, Judith L. Flippen-Anderson
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Anthracene Cyclopentadiene Flash vacuum pyrolysis General Medicine Adduct chemistry.chemical_compound Crystallography chemistry Nitro Organic chemistry Molecule Bridged compounds Alkyl
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199131113
Popis:	1,2-Difluorodinitroethylene was synthesized by flash vacuum pyrolysis of 1,2-difluorotetranitroethane. X-ray crystallography showed that one of the two nitro groups is out of the plane of the rest of molecule and that the C-C double-bond distance in unusually short at 1.284 {angstrom}. 1, 2-Difluorotetranitroethane reacted with alcohols to give alkyl fluoronitroacetates and with anthracene and cyclopentadiene to give Diels-Alder adducts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4b93689d3f6879836140662d769e45c https://doi.org/10.1002/chin.199131113 Zobrazit plný text záznamu Plný text