Synthesis of carboxylate arsenobetaines based on (carboxyalkyl)triphenylarsonium halides

Autor:	Vladimir I. Galkin, Irina V. Galkina, Alfiya F. Aksunova, Yu. V. Bakhtiyarova
Rok vydání:	2015
Předmět:	Triphenylarsine chemistry.chemical_compound chemistry Yield (chemistry) Dehydrohalogenation Halide Organic chemistry General Chemistry Carboxylate Antibacterial activity
Zdroj:	Russian Journal of General Chemistry. 85:2058-2064
ISSN:	1608-3350 1070-3632
Popis:	It has been found that the reaction of triphenylarsine with unsaturated carboxylic acids (acrylic, maleic, and itaconic ones) supposed to yield the arsenobetaines does not occur, in contrast to similar reactions of carboxylic acids with tertiary phosphines. However, the interaction of tertiary arsines with the halogenated carboxylic acids has resulted in the corresponding tertiary arsonium salts, dehydrohalogenation of the latter affording the target carboxylate betaines in the quantitative yield; the products structure has been elucidated using a set of chemical, physical, and physico-chemical methods. Antibacterial activity of the prepared compounds has been studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4b4f0882f74ddc0cc306434814af8f3 https://doi.org/10.1134/s1070363215090078 Zobrazit plný text záznamu Plný text ve formátu PDF