Control of the Regioselectivity in the Pauson−Khand Reaction of 7-Oxanorbornene Derivatives

Autor:	Aurelio G. Csaky, and M. Carmen Murcia, Odón Arjona, Joaquín Plumet
Rok vydání:	1999
Předmět:	Olefin fiber chemistry.chemical_compound chemistry Pauson–Khand reaction Organic Chemistry Substituent Organic chemistry Regioselectivity Halide
Zdroj:	The Journal of Organic Chemistry. 64:7338-7341
ISSN:	1520-6904 0022-3263
Popis:	The regiochemistry of the Pauson−Khand reaction of 7-oxanorbornene derivatives can be influenced by a remote substituent at carbon C-2. Furthermore, a remarkable effect on the regiochemical outcome of this reaction was observed by halide substituents in the olefin carbons, which may be utilized as an element of control of regioselectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4ac33d0c6882b6dc3b25392e9827dc4 https://doi.org/10.1021/jo9903095 Zobrazit plný text záznamu