Pd-Catalyzed Reduction of Aldehydes to Alcohols Using Formic Acid as the Hydrogen Donor

Autor:	Qingwen Gui, Ji-Cheng Shi, Anwei Wang, Jidan Liu, Xiang Chen, Zhiyong Yang, Ze Tan
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Hydrogen Formic acid Hydride Organic Chemistry Molecule chemistry.chemical_element Organic chemistry Selective reduction Catalysis
Zdroj:	Synthetic Communications. 44:280-288
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397911.2013.804575
Popis:	Facile and selective reduction of aromatic aldehydes as well as aliphatic aldehydes to alcohols was achieved using formic acid as the hydrogen donor in the presence of a catalytic amount of Pd(OAc)2 and Cy3P. It was found that both hydrogen atoms in the formic acid molecule can serve as the hydride source. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4a24cadcd1e2ce95cb2e69fcb2d8d65 https://doi.org/10.1080/00397911.2013.804575 Zobrazit plný text záznamu