On the Electronic Nature of Bis((Z)-1-(benzo[d]oxazol-2-yl)-3.3.3-trifluoroprop-1-en-2-ate)palladium

Autor:	Robert A. Gossage, Genki Watanabe, Masami Kawase, Ryosuke Saijo, Kathleen L. May
Rok vydání:	2019
Předmět:	Magnetic moment 010405 organic chemistry Ligand chemistry.chemical_element General Chemistry General Medicine 010402 general chemistry 01 natural sciences 0104 chemical sciences Crystallography chemistry Yield (chemistry) Drug Discovery Diamagnetism Density functional theory Spectroscopy Palladium
Zdroj:	Chemical and Pharmaceutical Bulletin. 67:498-500
ISSN:	1347-5223 0009-2363
Popis:	The electronic nature of the recently reported complex, bis((Z)-1-(benzo[d]oxazol-2-yl)-3.3.3-trifluoroprop-1-en-2-ate)palladium, is re-investigated by a combination of spectroscopy (NMR, IR, magnetic moment, etc.) and Density Functional Theory (DFT: B3LYP 6-31G*/LANL2DZ). In contrast to the recent report, the title complex displays all the properties of diamagnetism and hence retains the properties of a formally Pd(II) square planar complex with a bis-κ2-N,O-donor ligand set. A modified synthetic route is also presented which improves the yield of the compound.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4942b0fde48b374f4be872226011979 https://doi.org/10.1248/cpb.c18-00961 Zobrazit plný text záznamu