Evidence for Silica Surface Three- and Five-Membered Metallacycle Intermediates in the Catalytic Cycle of Hydroaminoalkylation of Olefins Using Single-Ti-Metal Catalysts
| Autor: | Jean-Marie Basset, Manal S. Al-Harbi, Jérémie D. A. Pelletier, Abdesslem Jedidi, Edy Abou-Hamad, Maha A. Aljuhani, Mohamad El Eter, Layal F. Yaacoub, Luigi Cavallo, Walid Al Maksoud, Wiebke Wackerow |
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| Rok vydání: | 2020 |
| Předmět: |
Tris
010405 organic chemistry Organic Chemistry Metallacycle 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound chemistry Catalytic cycle Group (periodic table) visual_art Polymer chemistry visual_art.visual_art_medium Metal catalyst Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 39:2438-2445 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | The single-site silica-supported group IV metal amido complex [Ti(NMe2)4] gives the tris(amido)-supported fragment [(≡Si–O−)Ti(−NMe2)3], which transforms into a three-membered metallacycle (called ... |
| Databáze: | OpenAIRE |
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