Mechanism of the dehydrogenation of the Hantzsch ether with pyridine N-oxide

Autor:	G. V. Kireev, A. S. Sadykov, Yu. V. Kurbatov, V. B. Leont'ev, O. I. Kartavtsev, O. S. Otroshchenko
Rok vydání:	1978
Předmět:	chemistry.chemical_compound chemistry Pyridine Pyridine-N-oxide Ether Dehydrogenation General Chemistry Limiting Photochemistry Acceptor Medicinal chemistry Ion
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:696-700
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925286
Popis:	A study has been made of the dehydrogenation of Hantzsch ethers by pyridlne N-oxide. A scheme proposed for this reaction shows the hydride-ion passing over into a complex of the Hantzsch ether with the N-oxide (limiting step), followed by rapid transfer of the H+ ion to the hydride-ion acceptor with elimination of water and the final reaction products.
Databáze:	OpenAIRE
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