T-x phase diagram of the In-S system
| Autor: | A. Yu. Zavrazhnov, E. G. Goncharov, P. V. Anorov, A. V. Naumov, Vladislav S. Pervov, V. I. Sidei |
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| Rok vydání: | 2006 |
| Předmět: | |
| Zdroj: | Inorganic Materials. 42:1294-1298 |
| ISSN: | 1608-3172 0020-1685 |
| DOI: | 10.1134/s0020168506120028 |
| Popis: | The T - x phase diagram of the In-S system has been studied by differential thermal analysis and x-ray diffraction between 300 and 1150 ° C. The compounds identified in this temperature range are InS, In 6 S 7 , In 3 S 4 , and In 2 S 3 . We have determined the temperatures of the monotectic equilibrium L 1 (In) + InS = L 2 ; peri- tectic equilibria involving InS, In 6 S 7 , and In 3 S 4 ; and polymorphic transformations of InS and In 2 S 3 . Our results demonstrate that raising the cooling rate to a certain level leads to a sharp transition from near-equilibrium to metastable phase relations in the In-S system. |
| Databáze: | OpenAIRE |
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