An electrochemical technique for the reduction of aromatic nitro compounds

Autor: M. Noel, P. N. Anantharaman, H. V. K. Udupa
Rok vydání: 1982
Předmět:
Zdroj: Journal of Applied Electrochemistry. 12:291-298
ISSN: 1572-8838
0021-891X
DOI: 10.1007/bf00615094
Popis: A preparative technique for the electroreduction of aromatic nitro compounds using a copper cathode, a lead anode and a porous pot diaphragm with 30–40% H2SO4 as the anolyte and 30–40% H2SO4 containing 2–3% Ti(SO4)2 as the catholyte is reported. Nitrobenzene, dinitrobenzenes, nitrotoluenes, phenols, phenetoles and nitrochlorobenzenes have been reduced by this method. Slightly modified techniques were employed for some compounds such as 2-nitro-m-xylene. The results of some pilot plant studies are also reported. The studies indicate that on smaller scales this technique may be competitive with metal/acid systems with the additional advantage of less pollution problems.
Databáze: OpenAIRE