Evolution of Luminescence with Shell's Thickness in Colloidal CdSe/CdS

Autor: Shen Li, YE Yong-Hong, Wang Zhi-Bing, Zhang Jia-Yu, Liang Da-Shun, Cui Yi-Ping
Rok vydání: 2008
Předmět:
Zdroj: Chinese Physics Letters. 25:4431-4434
ISSN: 1741-3540
0256-307X
DOI: 10.1088/0256-307x/25/12/069
Popis: We synthesize colloidal CdSe/CdS core/shell quantum dots with different shell thicknesses, and there are five samples including CdSe core dots, and CdSe/CdS core/shell dots with 1–4 CdS layers. X-ray diffraction and Raman measurements indicate that the stress in CdSe core becomes stronger with the increasing shell thickness, and the optical measurements show that when the shell becomes thicker, the photoluminescence quantum yield is enhanced, and the radiative decay is also expedited. The temperature-dependent optical spectra are measured. The relation between the microstructure and the optical properties is discussed.
Databáze: OpenAIRE