Synthesis and Characterisation of Schiff Base-like Iron(II) Complexes with Imidazole as Axial Ligand

Autor:	Stephan Schlamp, Birgit Weber, Peter Thoma, Wolfgang Bauer, Charles Lochenie
Rok vydání:	2011
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography Schiff base Octahedron Chemistry Stereochemistry Ligand Spin crossover Hydrogen bond Imidazole Atmospheric temperature range Magnetic susceptibility
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 638:98-102
ISSN:	0044-2313
Popis:	Four new six-coordinate and one pentacoordinate iron(II) complexes with imidazole as axial ligand were synthesised and characterised. For two of the complexes crystals suitable for X-ray structure analysis were obtained and an extended network of hydrogen bonds was observed in both cases. Magnetic susceptibility studies revealed, that two of the octahedral complexes are high-spin complexes in the entire temperature range, whereas for the other two gradual spin transitions are observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c43ace3a9854979fd814396570140adb https://doi.org/10.1002/zaac.201100424 Zobrazit plný text záznamu Plný text