A New Analysis Method for Quantitative Determination of Triads of Copoly(substituted acetylene) Backbones by Highly Selective Photocyclic Aromatization
| Autor: | Guanwu Yin, Masahiro Teraguchi, Lijia Liu, Takashi Kaneko, Toshiki Aoki, Nennei Nagaoka |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Aromatization
Triad (anatomy) 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Highly selective 01 natural sciences Quantitative determination 0104 chemical sciences chemistry.chemical_compound medicine.anatomical_structure Acetylene chemistry medicine Copolymer Organic chemistry 0210 nano-technology Quantitative analysis (chemistry) Analysis method |
| Zdroj: | Chemistry Letters. 46:1608-1611 |
| ISSN: | 1348-0715 0366-7022 |
| DOI: | 10.1246/cl.170697 |
| Popis: | Since highly selective photocyclic aromatization (SCAT) of poly(substituted acetylene)s yields quantitatively the corresponding 1,3,5-trisubstituted benzene derivatives, the SCAT products were applied for quantitative determination of microstructures of copoly(substituted acetylene)s by NMR (nuclear magnetic resonance). By this SCAT-NMR method for two copolymers of two different types of substituted acetylenes, quantitative analysis for microstructures, i.e., triad distributions and compositions, have been achieved successfully under mild conditions, although they could not be obtained from the NMR of the original copolymers because of their broad and overlapped peaks. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|