Modular Dihydrobenzoazaphosphole Ligands for Suzuki–Miyaura Cross-Coupling

Autor:	Amy R. Howell, Yibo Xu, Heewon Lee, Nizar Haddad, Yongda Zhang, Zhengxu S. Han, Jean-Nicolas Desrosiers, Jinhua J. Song, Nathan K. Yee, Linglin Wu, Xiao-Jun Wang, Kendricks S. Lao, Chris H. Senanayake, Joshua D. Sieber
Rok vydání:	2018
Předmět:	Coupling 010405 organic chemistry Chemistry Ligand Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Phosphine Palladium
Zdroj:	Synthesis. 50:4429-4434
ISSN:	1437-210X 0039-7881
Popis:	A new family of dihydrobenzoazaphosphosphole ligands was prepared and shown to enable modification of the phosphine electronic character by variation of the N-substituent. This new family of phosphines was shown to be highly active in the Pd-catalyzed Suzuki–Miyaura cross-coupling reaction with hindered coupling partners.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c3ea0b80e236b6de4ea5024dd0433094 https://doi.org/10.1055/s-0037-1610158 Zobrazit plný text záznamu