Generation and Use of an Equivalent of Difluoroacetamide or Difluoroacetate Anions Part 3 of the Series: Reactivity of Stable Trifluoroacetaldehyde hemiaminals. Part 2: T. Billard, B. R Langlois, J. Org. Chem. 2002, 67, 997–1000

Autor:	Thierry Billard, Gaëlle Blond, Bernard Langlois
Rok vydání:	2002
Předmět:	Nucleophilic addition Chemistry Computational chemistry Organic Chemistry Electrophile Nucleophilic substitution Organic chemistry General Chemistry Catalysis
Zdroj:	Chemistry - A European Journal. 8:2917
ISSN:	1521-3765 0947-6539
Popis:	Ethers of trifluoroacetaldehyde hemiaminals can undergo dehydrofluorination under basic conditions to provide ethers of difluoroketene hemiaminals. The latter behave as equivalents of difluoroacetamide or difluoroacetate anions towards various electrophiles, yielding a range of difluoromethylcarbonyl products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c3c0ff5b1f20ea5a38140a20c339dc54 https://doi.org/10.1002/1521-3765(20020703)8:13<2917::aid-chem2917>3.0.co Zobrazit plný text záznamu Plný text