Enthalpies of Anion Exchange of Chloride by Pyridinecarboxylate in AV-17-8 Anionite
| Autor: | E. V. Ostapova, G. N. Al’tshuler, O. G. Al’tshuler |
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| Rok vydání: | 2019 |
| Předmět: |
Isothermal microcalorimetry
Aqueous solution Ion exchange Chemistry Enthalpy Inorganic chemistry Sorption 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Dipicolinic acid 01 natural sciences Chloride 0104 chemical sciences chemistry.chemical_compound medicine Physical and Theoretical Chemistry 0210 nano-technology medicine.drug |
| Zdroj: | Russian Journal of Physical Chemistry A. 93:743-747 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s0036024419040034 |
| Popis: | Enthalpies of Cl– anion exchange for anions of nicotinic, isonicotinic, dipicolinic, and cinchomeronic acids on the strongly basic anionite AV-17-8 are measured at 298 K by means of microcalorimetry. Partial and standard enthalpies of sorption of pyridinecarboxylic acid anions on the Cl-form of AV-17-8 anionite from aqueous solutions are determined. The values of standard enthalpies lie in the range 3–14 kJ/mol, increasing in the order nicotinate, isonicotinate, dipicolinic acid anions, and cinchomeronic acid anions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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