Defect and impurity effects on the initial growth of Ag on Si(111)

Autor: J. F. Wendelken, J.‐K. Zuo
Rok vydání: 1991
Předmět:
Zdroj: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 9:1539-1544
ISSN: 1520-8559
0734-2101
DOI: 10.1116/1.577658
Popis: Step and impurity effects on the initial growth of a thin film have been demonstrated in the ( 7/8 × 7/8 )R30° (or simply 7/8 ) domain growth of Ag on Si(111) using high angular resolution low‐energy electron diffraction. Anisotropy in the 7/8 domain shape and growth during deposition are found on the stepped Si(111) with the preferential growth along the step edge direction. The 7/8 superlattice grows with coverage principally by domain coalescence at the temperature T∼450 °C and is self‐similar at different coverages (scaling) as observed on a flat Si(111). The size distribution is shown to follow a Gamma distribution by a simple model calculation. A dramatic change in the growth mechanism is observed when oxygen impurities [≤0.02 monolayer] appear. The 7/8 domains in the presence of impurities grow with coverage more randomly and isotropically in contrast with the step edge effects and coalescence is inhibited. As a result, the 7/8 superlattice stays in a microdomain morphology without long range order.
Databáze: OpenAIRE