Reaction of chloro(ethyl)silanes with chloro(phenyl)silanes in the presence of aluminum chloride. Synthesis of chloro(ethyl)(phenyl)silanes

Autor:	A. D. Kirilin, V. G. Bykovchenko, N. V. Ushakov, M. I. Eremeeva, V. G. Lakhtin, E. G. Gordeev, E. A. Chernyshev
Rok vydání:	2015
Předmět:	Silanes Substituent chemistry.chemical_element Disproportionation General Chemistry Chloride Medicinal chemistry chemistry.chemical_compound chemistry Aluminium Yield (chemistry) medicine Organic chemistry Probable mechanism medicine.drug
Zdroj:	Russian Journal of General Chemistry. 85:595-599
ISSN:	1608-3350 1070-3632
Popis:	Substituent exchange at the silicon atom between chloro(phenyl)silanes (PhSiCl3, MePhSiCl2, Ph2SiCl2) and chloro(ethyl)silanes (EtSiCl3, Et2SiCl2, Et3SiCl, Et4Si) in the presence of aluminum chloride has been studied. The examined compounds, except for PhSiCl3 and Et4Si, react fairly readily to give chloro(ethyl)-(phenyl)silanes in up to 48–52% yield. A probable mechanism has been proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c3a67b19b29be1f4877eecb2c01d0a07 https://doi.org/10.1134/s1070363215030111 Zobrazit plný text záznamu Plný text ve formátu PDF