Preparation of pyrazoles and pyrazolines by the reaction of chlorocyclopropanols with hydrazines in the presence of crown ethers

Autor: V. M. Shostakovskii, V. N. Mochalov, Oleg M. Nefedov, T. K. Voropaeva, S. M. Shostakovskii
Rok vydání: 1985
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:218-220
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf01157367
Popis: The reaction of gem-dichlorocyclopropanol with hydrazine and phenylhydrazine in the presence of crown ethers at 20‡C leads to the formation of the corresponding pyrazoles in yields up to 60%. Under analogous conditions, cis- and trans-chlorocyclopropanols and phenylhydrazine give N-phenylpyrazoline in 58% yield.
Databáze: OpenAIRE