Synthesis, Characterization, and Reactivities of Molybdenum and Tungsten PONOP Pincer Complexes
| Autor: | Lloyd Munjanja, Sumit Chakraborty, William D. Jones, Ruth Castro-Rodrigo, William W. Brennessel |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Hydride Organic Chemistry chemistry.chemical_element Tungsten 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Pincer movement Inorganic Chemistry Metal chemistry.chemical_compound Deprotonation chemistry Molybdenum visual_art Polymer chemistry Pyridine visual_art.visual_art_medium Physical and Theoretical Chemistry Isomerization |
| Zdroj: | Organometallics. 35:3124-3131 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.6b00461 |
| Popis: | A new series of molybdenum and tungsten tricarbonyl pincer complexes, bearing pyridine-based PONOP-type pincer ligands, have been synthesized and fully characterized. Addition of HBF4·Et2O to these tricarbonyl complexes generated seven-coordinate molybdenum and tungsten hydride complexes, and these compounds have been isolated in good yields. These metal hydrides show fluxional behavior in solution. The hydride ligands on these metal complexes are acidic in nature and are readily deprotonated by bases. The molybdenum hydride complex is shown to catalyze isomerization of 1-hexene to internal isomers under mild conditions. |
| Databáze: | OpenAIRE |
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