Benzene benzimidazole containing Pd(II) metallacycle: Synthesis, X-ray crystallographic characterization and its use as an efficient Suzuki coupling catalyst

Autor:	Wen-Shu Hwang, Sachindranath Pal, Chen-Shiang Lee, Ivan J. B. Lin
Rok vydání:	2007
Předmět:	Benzimidazole Process Chemistry and Technology X-ray chemistry.chemical_element Metallacycle Catalysis Ion chemistry.chemical_compound Crystallography chemistry Suzuki reaction Physical and Theoretical Chemistry Benzene Palladium
Zdroj:	Journal of Molecular Catalysis A: Chemical. 269:197-203
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2007.01.028
Popis:	A first example of a highly stable benzimidazole N-donor dinuclear palladacycle complex is reported. X-ray diffraction analysis showed that two ligands assembled through complexation to two palladium(II) ions to give a compressed rectangular shaped metallamacrocycle. This complex catalyzed Suzuki coupling reaction effectively in MeOH at room temperature. Hg(0) poisoning test supports the formation of L-Pd(0) species in the catalytic reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c36f4f33a2d5bfb279249e9fbd2523ac https://doi.org/10.1016/j.molcata.2007.01.028 Zobrazit plný text záznamu Full Text from ScienceDirect