A Convenient Synthesis ofS-AlkylO-Aryl Thiophosphoric Acid Derivatives

Autor:	Gaoju Zhang, Chuchi Tang, Gui-Ping Wu
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Base (chemistry) Phosphorus Aryl Organic Chemistry chemistry.chemical_element Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Nucleophile Thiophosphoric acid Isomerization Alkyl
Zdroj:	Synthesis. 1991:454-456
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-1991-26491
Popis:	A new convenient synthesis of S-alkyl O-aryl thiophosphoric acid derivatives is reported. The chlorination of O-aryl O,O-dialkyl thiophosphates with phosphorus oxychloride proceeds with isomerization to give S-alkyl O-aryl thiophosphorochloridates, which react further with various nucleophiles in the presence of base to give the title compounds
Databáze:	OpenAIRE
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