Chromium(III)-Catalyzed C(sp2)–H Alkynylation, Allylation, and Naphthalenation of Secondary Amides with Trimethylaluminum as Base
| Autor: | Mengqing Chen, Eiichi Nakamura, Rui Shang, Hlib Razumkov, Takenari Sato, Takahiro Doba, Laurean Ilies |
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| Rok vydání: | 2020 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Base (chemistry) Low toxicity Chemistry technology industry and agriculture chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry Catalysis 0104 chemical sciences Chromium Colloid and Surface Chemistry Alkynylation otorhinolaryngologic diseases Base metal |
| Zdroj: | Journal of the American Chemical Society. 142:4883-4891 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | Among base metals used for C–H activation reactions, chromium(III) is rather unexplored despite its natural abundance and low toxicity. We report herein chromium(III)-catalyzed C(sp2)–H functionali... |
| Databáze: | OpenAIRE |
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