Measurement of surface forces between mica sheets immersed in aqueous quaternary ammonium ion solutions

Autor:	Per M. Claesson, Richard M. Pashley, R. G. Horn
Rok vydání:	1984
Předmět:	Aqueous solution Chemistry Surface force Inorganic chemistry Electrostatics Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Biomaterials chemistry.chemical_compound Colloid and Surface Chemistry Adsorption Ammonium Mica Large size
Zdroj:	Journal of Colloid and Interface Science. 100:250-263
ISSN:	0021-9797
DOI:	10.1016/0021-9797(84)90433-8
Popis:	Forces between mica surfaces immersed in Me4NBr, Pr4NBr, and Pe4NBr solutions over a wide concentration range are reported (Me = methyl, Pr = propyl, Pe = pentyl). In each case the cation adsorbs quite strongly onto the negatively charged mica surface and determines the double-layer potential. However, this strong adsorption does not cause complete neutralization of the negative lattice charge apparently because of packing constraints due to the large size of these ions. Adsorption of Me4N+ ions gives rise to a short-range (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c32c7ddb14ee525f8cd115031c8345ef https://doi.org/10.1016/0021-9797(84)90433-8 Zobrazit plný text záznamu