A simple and efficient protocol for epoxidation of olefins using dimethyldioxirane

Autor:	Tiago O. Vieira, Rozanna M. Muzzi, Hans Viertler, Helena M. C. Ferraz
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Aqueous solution chemistry Organic Chemistry Drug Discovery Acetone Substrate (chemistry) Organic chemistry Dimethyldioxirane Biochemistry
Zdroj:	Tetrahedron Letters. 41:5021-5023
ISSN:	0040-4039
Popis:	The reaction of a series of monoterpenic olefins and Δ4-octalins with dimethyldioxirane led to the corresponding epoxides in excellent yields. Remarkable diastereoselectivity was observed for the Δ4-octalins. The procedure consists simply in stirring the substrate, NaHCO3 and acetone, at 0°C, with dropwise addition of an aqueous solution of oxone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c31feff7c188ac4a01817353dec2afb3 https://doi.org/10.1016/s0040-4039(00)00769-3 Zobrazit plný text záznamu Full Text from ScienceDirect