Photosonosynthesis of 1,2,4-tris(methylthio)-3-H-hexafluoro-n-butane

Autor:	Madeline S. Toy, Roger S. Stringham
Rok vydání:	1985
Předmět:	Tris Reaction mechanism Stereochemistry Organic Chemistry Butane Methanethiol Hydrogen fluoride Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Microwave chemistry Environmental Chemistry Physical and Theoretical Chemistry Aliphatic compound Isomerization
Zdroj:	Journal of Fluorine Chemistry. 29:253-260
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(00)82325-8
Popis:	The preparation of neat 1,2,4-tris(methylthio)-3-H-hexafluoro-n-butane is described. The mechanism, which involves the elimination of hydrogen fluoride with the subsequent isomerization in forming the cis - and trans- 1,2,4-tris(methylthio)hexafluoro-l-butene, is discussed. This study also supports the presence of methanethiol as an intermediate during the photosonoreaction of bis(methylthio)hexafluoro-2-butene with an excess of methyl disulfide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c31c19b08e8888765d1c9abd27b4b936 https://doi.org/10.1016/s0022-1139(00)82325-8 Zobrazit plný text záznamu