Rearrangement of? -trifluoromethyl-?-dialkylamino-?-fluoroacrylic acid N.N-dialkylamides

Autor:	E. I. Mysov, E. M. Rokhlin, I. L. Knunyants, U. Utebaev
Rok vydání:	1976
Předmět:	chemistry.chemical_compound Trifluoromethyl Chemistry Organic chemistry General Chemistry Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:124-128
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925633
Popis:	When heated in the presence of a catalytic amount of BF3 etherate,α-trifluoromethyl-β-diethylamino-β-fluoroacrylic acid N, N-dimethylamide is reversibly isomerized toα-trifluoromethyl-β-dimethylamino-β-fluoroacrylic acid N, N-diethylamide. The methyl esters ofα-trifluoromethyl-β-diethylammo-β-fluoroacrylic acid andα-trifluoromethyl-β-phenoxy-β-fluoroacrylic acid N,N-dimethylamide are not isomerized under the same conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c31675504902ba4fc80bb34d1d065120 https://doi.org/10.1007/bf00925633 Zobrazit plný text záznamu Full text from SpringerLink