Selective, Sensitive, and Reversible Detection of Vapor-Phase High Explosives via Two-Dimensional Mapping: A New Strategy for MOF-Based Sensors

Autor:	Xiao Zhang, Zhichao Hu, Sanhita Pramanik, Yves J. Chabal, Jing Li, Kui Tan, Wei Liu, Chong Zheng
Rok vydání:	2013
Předmět:	In situ Analyte Ethylene Explosive material Vapor phase Inorganic chemistry Analytical chemistry Infrared spectroscopy General Chemistry Condensed Matter Physics Fluorescence chemistry.chemical_compound chemistry General Materials Science Spectroscopy
Zdroj:	Crystal Growth & Design. 13:4204-4207
ISSN:	1528-7505 1528-7483
DOI:	10.1021/cg4012185
Popis:	A new strategy has been developed for the effective detection of high explosives in vapor phase by fluorescent metal–organic framework (MOF) sensors. Two structurally related and dynamic MOFs, (Zn)2(ndc)2P·xG [ndc = 2,6-naphthalenedicarboxylate; P =1,2-bis(4-pyridyl)ethane (bpe) or 1,2-bis(4-pyridyl)ethylene (bpee); G = guest/solvent molecule], exhibit a two-dimensional signal response toward analytes of interest in the vapor phase, including aromatic and aliphatic high explosives (e.g., TNT and RDX). The interaction between analytes and the MOF has been studied using in situ infrared absorption spectroscopy and a DFT computational method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c30f9e6ca82f4c7c541215a0c077bbf5 https://doi.org/10.1021/cg4012185 Zobrazit plný text záznamu