| Autor: |
Thomas A. Spiglanin, David Chandler, David H. Parker |
| Rok vydání: |
1987 |
| Předmět: |
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| Zdroj: |
Chemical Physics Letters. 137:414-420 |
| ISSN: |
0009-2614 |
| DOI: |
10.1016/0009-2614(87)80225-7 |
| Popis: |
We report 2 + 1 resonantly enhanced multiphoton ionization spectra of HCl between 82000 and 89000 cm −1 two-photon energy with mass resolution of the ions. We see significant production of atomic products subsequently ionized when the two-photonresonant state has a long bond length but we see only HCl + when the resonant state is of Rydberg origin (and hence has a short bond length). The state at 82780 cm −1 , assigned as the E 1 Σ + (ν = 0) state, exhibits the production of atoms that is characteristic of a state with a long bond length, evidence that this state should be incorporated into the double-minimum B 1 Σ + state. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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