Nitroxide radicals. Part 21. Spontaneous decomposition of N-aryl 1- and 2-naphthyl nitroxides

Autor:	Gordon McConnachie, Joseph D. Fullerton, Alexander R. Forrester
Rok vydání:	1983
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Nitroxide mediated radical polymerization Chemistry Ylide Aryl Radical Imine Nitroxyl Reaction intermediate Photochemistry Medicinal chemistry Benzoquinone
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :1759
ISSN:	1364-5463 0300-922X
Popis:	N-Aryl 1-naphthyl nitroxides self-react in solution to give the corresponding secondary amines and N-aryl-1,4-naphthoquinone imines. When reaction at the 4-naphthyl position is hindered by substituents benzoquinone imines are also produced. N-Phenyl 2-naphthyl nitroxide under similar conditions gives the corresponding amine and 2-phenylamino-1,4-naphthoquinone via a 1,2-naphthoquinone imine N-oxide intermediate.
Databáze:	OpenAIRE
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