Bis(tributyltin) oxide as a wood preservative: Its conversion to tributyltin carboxylates inPinus sylvestris

Autor:	R. Hill, S J Blunden
Rok vydání:	1990
Předmět:	Inorganic Chemistry Pinus chemistry.chemical_compound Preservative 13c nmr spectroscopy Softwood chemistry Tributyltin oxide Tributyltin Oxide Disproportionation General Chemistry Nuclear chemistry
Zdroj:	Applied Organometallic Chemistry. 4:63-68
ISSN:	1099-0739 0268-2605
DOI:	10.1002/aoc.590040111
Popis:	Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber has not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide [(Bu3Sn)2O] is rapidly converted to tributyltin carboxylates (Bu3SnOCO·R) via reaction with components of the wood resin. It is further suggested that the formation of these species is a prerequisite for the known disproportionation reaction which occurs in (Bu3Sn)2O-treated timber.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c2cf8ef1f210b8687dae50ffc30f7272 https://doi.org/10.1002/aoc.590040111 Zobrazit plný text záznamu Plný text