Investigations of Complexes of Copper(II) Chloride with Phenylpyrazoles
| Autor: | M. J. Grabowski, Magdalena Małecka, M. Strawiak, K. Kostka, T. A. Olszak |
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| Rok vydání: | 1998 |
| Předmět: |
Stereochemistry
Hydrogen bond Intermolecular force chemistry.chemical_element General Medicine Crystal structure Copper General Biochemistry Genetics and Molecular Biology Square pyramidal molecular geometry Crystallography chemistry.chemical_compound chemistry Intramolecular force Copper(II) chloride Molecule |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 54:1770-1773 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270198008786 |
| Popis: | The crystal structures of dichlorobis(3,5-diphenylpyrazole-N2)copper(II), [CuCl2(C15H12N2)2], (I), dichlorobis(5-phenylpyrazole-N2)copper(II), [CuCl2(C9H8N2)2], (II), and dichlorobis(1-phenylpyrazole-N2)copper(II), [CuCl2(C9H8N2)2], (III), have been determined from X-ray diffraction data. There are significant differences in the coordination of the Cl− ions to the Cu2+ ion. The coordination of the Cu2+ ion is distorted square pyramidal in compounds (I) and (II), and distorted tetrahedral in (III). All available N—H groups form hydrogen bonds, which are intra- and intermolecular in (I), and intramolecular in (II). An N—H group in (I) forms a bifurcated hydrogen bond. Intermolecular intereactions between neighbouring molecules form dimers and chains in (I) and (II), respectively. |
| Databáze: | OpenAIRE |
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