Preparation of 5‐Aryl‐3‐Oxo‐δ‐Lactones by the Potassium Carbonate–Promoted Condensation of Aromatic Aldehydes and Ethyl Acetoacetate in Ethanol

Autor:	Carl Stanley, Jessica Gereg, Mical Amanuel, Brad Andersh
Rok vydání:	2008
Předmět:	Potassium carbonate Benzaldehyde chemistry.chemical_compound Ethanol Chemistry Potassium Aryl Ethyl acetoacetate Organic Chemistry Nitro Alkoxy group chemistry.chemical_element Organic chemistry
Zdroj:	Synthetic Communications. 38:482-488
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397910701796493
Popis:	5‐Aryl‐3‐oxo‐δ‐lactones (6‐aryl‐dihydro‐2H‐pyran‐2,4(3H)‐diones) were prepared by the potassium carbonate–promoted condensation of aromatic aldehydes and ethyl acetoacetate in absolute ethanol. Benzaldehyde and substituted benzaldehydes bearing an alkoxy group (2 or 3 position), a chlorine atom (2, 3, or 4 position), a nitro group (3 or 4 position), a cyano group (4 position), or an acetyl group (4 position) react in high yields under these conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c2b107820bf30afcf25373cb0e4b46fb https://doi.org/10.1080/00397910701796493 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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