Synthesis of stable diphenyl-di(germylene) and diphenyl-di(plumbylene)

Autor:	Dennis Heitmann, Julia V. Dickschat, F. Ekkehardt Hahn, Tania Pape
Rok vydání:	2013
Předmět:	Inorganic Chemistry Computational chemistry Chemistry Organic Chemistry Intermolecular force Materials Chemistry Physical and Theoretical Chemistry Biochemistry Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. 744:160-164
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2013.06.016
Popis:	Reaction of the 3,3′,4,4′tetra(alkylamino) diphenyl 2 with 2 equiv of Ge[N(TMS)2]2 or Pb[N(TMS)2]2 lead to the formation of the rigid ditopic digermylene 3 and diplumbylene 4, respectively. The molecular structures of 3 and 4 have been determined by X-ray diffraction methods revealing intermolecular E⋯Ar (E = Ge, Pb) interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c29556e7204efeacabfc09419ba465ef https://doi.org/10.1016/j.jorganchem.2013.06.016 Zobrazit plný text záznamu Full Text from ScienceDirect