Spectroscopic properties of the vanadium(III) tris(metaphosphate), V(PO)

Autor:	F. Guillen, Teófilo Rojo, José L. Mesa, J. M. Rojo, R. Olazcuaga, Luis Lezama
Rok vydání:	1998
Předmět:	Tris Metaphosphate Inorganic chemistry Weak signal Vanadium chemistry.chemical_element Infrared spectroscopy Crystal structure Ion chemistry.chemical_compound Crystallography chemistry Materials Chemistry Monoclinic crystal system
Zdroj:	Annales de Chimie Science des Mat�riaux. 23:107-111
ISSN:	0151-9107
DOI:	10.1016/s0151-9107(98)80034-2
Popis:	A vanadium(III) tris(metaphosphate) compound has been synthesized and characterized. The compound crystallises in the monoclinic space group Ic with lattice parameters a= 10.615(2), b= 19.095(4), c= 9.432(1) A, β= 97.94(1) °. IR and UV-V studies confirm a chain structure for this compound. The ESR powder spectrum shows a weak signal belonging to the V3+ ions. The D parameter value has been estimated between 2 and 8 cm−1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c24f835fbe4b9f1fbdd464778e8f7a94 https://doi.org/10.1016/s0151-9107(98)80034-2 Zobrazit plný text záznamu