Spectroscopic properties of the vanadium(III) tris(metaphosphate), V(PO)
Autor: | F. Guillen, Teófilo Rojo, José L. Mesa, J. M. Rojo, R. Olazcuaga, Luis Lezama |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Annales de Chimie Science des Mat�riaux. 23:107-111 |
ISSN: | 0151-9107 |
Popis: | A vanadium(III) tris(metaphosphate) compound has been synthesized and characterized. The compound crystallises in the monoclinic space group Ic with lattice parameters a= 10.615(2), b= 19.095(4), c= 9.432(1) A, β= 97.94(1) °. IR and UV-V studies confirm a chain structure for this compound. The ESR powder spectrum shows a weak signal belonging to the V3+ ions. The D parameter value has been estimated between 2 and 8 cm−1. |
Databáze: | OpenAIRE |
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