Temperature Dependence of the ESR Spectrum from a Tunneling Methyl Group

Autor:	R. B. Davidson, Ichiro Miyagawa
Rok vydání:	1972
Předmět:	Chemistry Radical General Physics and Astronomy Molecular physics Spectral line law.invention chemistry.chemical_compound Nuclear magnetic resonance law Radiolysis Irradiation Physical and Theoretical Chemistry Electron paramagnetic resonance Maxima Hyperfine structure Methyl group
Zdroj:	The Journal of Chemical Physics. 57:1815-1817
ISSN:	1089-7690 0021-9606
Popis:	The electron spin resonance spectrum for the unstable radical CH3ĊHR in irradiated L‐alanine was observed from 4.2–80°K. The hyperfine lines for MI = ± 1/2 showed relative maxima in peak intensity at 11°K when partially saturated. The presence of the maxima is interpreted in terms of spin‐diffusion and Brownian mixing.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c236e0ca78452c0f78fde60183ae4c07 https://doi.org/10.1063/1.1678494 Zobrazit plný text záznamu