A versatile synthesis of cyclic molybdenum– and tungsten–carbon σ-bonded complexes

Autor:	S. B. Wild, K. P. Wainwright
Rok vydání:	1972
Předmět:	Hydride Inorganic chemistry Cationic polymerization chemistry.chemical_element Tungsten Sodium amalgam Elimination reaction chemistry.chemical_compound chemistry Molybdenum Polymer chemistry Molecular Medicine Derivative (chemistry) Tetrahydrofuran
Zdroj:	J. Chem. Soc., Chem. Commun.. :571-572
ISSN:	0022-4936
DOI:	10.1039/c39720000571
Popis:	A simple dehalogenation takes place when dicarbonyl-(3-chloropropyldimethylarsine)-η-cyclopentadienyliodomolybdenum(II) is treated in tetrahydrofuran with sodium amalgam; the cyclic Mo–C compound so formed undergoes an hydride elimination reaction to give a cationic derivative of chelated allyldimethylarsine.
Databáze:	OpenAIRE
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