Influence of pseudohalide anions on the structural assembly of Cd(II) coordination polymers with 3,4-bis(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
| Autor: | Jian-Hua Guo, Nan Sun, Ming-Ze Li, Jing Chen |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Thiocyanate 010405 organic chemistry Ligand Stereochemistry Organic Chemistry 1 2 4-Triazole 010402 general chemistry 01 natural sciences Fluorescence 0104 chemical sciences Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Azide Isostructural Dicyanamide Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1105:273-278 |
| ISSN: | 0022-2860 |
| Popis: | Four CdII coordination polymers, namely {[Cd(L334)(Cl)2](CH3OH)}n (1), [Cd(L334)(Cl)(dca)]n (2), {[Cd(L334)(Cl)1.33(N3)0.67](H2O)}n (3), and {[Cd(L334)(SCN)2(H2O)](H2O)1.5(CH3OH)}n (4), have been synthesized by the conventional reactions of CdCl2 and 3,4-bis(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (L334) or in the presence of different pseudohalides dicyanamide (dca), azide (N3), and thiocyanate (SCN), respectively as auxiliary ligands. Complexes 1–3 exhibit the isostructural 2D layered network structures, whereas complex 4 shows a distinct 2D network with dimeric CdII subunits. The structural discrepancy in 1–4 indicates the significant influence of pseudohalide anions on the structural assembly of CdII coordination polymers with 3,4-bis(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole. In addition, thermogravimetric and fluorescent properties for all complexes and the ligand have also been investigated. |
| Databáze: | OpenAIRE |
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