A Disposable Homemade Screen Printed Electrochemical Sensor for Vitamin B1 Determination in Multivitamin Ampoules: Potentiometric and Surface Morphology Studies
| Autor: | Ahmed S. Abo Dena, Omaima E. Sherif, Yousry M. Issa |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Scanning electron microscope
Chemistry 010401 analytical chemistry Potentiometric titration Analytical chemistry 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Chloride Ampoule 0104 chemical sciences Analytical Chemistry Electrochemical gas sensor Standard addition Screen printing Electrochemistry medicine Graphite 0210 nano-technology medicine.drug |
| Zdroj: | Electroanalysis. 29:1426-1433 |
| ISSN: | 1040-0397 |
| DOI: | 10.1002/elan.201700034 |
| Popis: | Thiamine chloride hydrochloride (TCH) is one of the B-complex vitamins which resemble a very biologically important group of biomolecules. The first screen-printed graphite ion-selective sensor for the determination of TCH was prepared and characterized. The sensor is based on TCH-tetraphenylborate as electrode material. A number of parameters such as the type of solvent mediator, weight percent of the ion-exchanger, test solution temperature and possible interferences were extensively studied. Moreover, the surface morphology of the prepared sensor was studied using scanning electron microscopy. The sensor shows a Nernstian slope of 30.60±0.07 mV/decade, a low LOD of 5.08×10−6 mol/L and a wide applicability range of 5.96×10−6-1.00×10−2 mol/L. The sensing graphite ink remains usable for at least one month. Fast potentiometric response was obtained within 5 s and remains stable for at least 60 s. The sensor was applied to the analysis of TCH in pure solutions and multivitamin ampoules from the Egyptian market using the standard addition method and high recovery values of 97–102 % were obtained. Low %RSD values (0.27-1.30) indicate high precision of the proposed sensor. Our sensor provides the advantages of disposability, simple preparation procedures, sensitivity and easy storage and transportation. |
| Databáze: | OpenAIRE |
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