Modeling study of two-step photodissociation method of isotope enrichment

Autor:	W. C. Hwang, C. C. Badcock, R. F. Kamada
Rok vydání:	1977
Předmět:	Bromine Isotope Organic Chemistry Photodissociation Analytical chemistry chemistry.chemical_element Kinetic energy Biochemistry Diatomic molecule Dissociation (chemistry) Inorganic Chemistry chemistry Chemical physics Physical and Theoretical Chemistry Scavenging Excitation
Zdroj:	International Journal of Chemical Kinetics. 9:969-982
ISSN:	1097-4601 0538-8066
DOI:	10.1002/kin.550090611
Popis:	A general comprehensive model of the two-step photodissociation method of isotope enrichment for diatomic reactants was constructed. The model includes kinetic and absorption processes, isotopic species, and temperature. Criteria to measure different aspects of enrichment were established. The results show that, in general, isotopic mixing by kinetic processes can be controlled. The relative importance of intensities of excitation sources for the two steps depends on the degree of saturation of the first-step absorption transition. For the specific system modeled, i.e., the dissociation of HBr followed by scavenging with NO, the model predicts that detection of bromine enrichment is possible. The important processes and their influence on enrichment were identified, and optimization of experimental parameters was modeled.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c1ed458e74b4b439da0082b9a90d6ac5 https://doi.org/10.1002/kin.550090611 Zobrazit plný text záznamu Plný text