Probing the use of small-angle light scattering for characterizing structure of titanium dioxide/low-density polyethylene nanocomposites
| Autor: | Linda S. Schadler, Zhicheng Xiao, Ying Li, Dongling Ma, Yvonne A. Akpalu |
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| Rok vydání: | 2006 |
| Předmět: |
Materials science
Polymers and Plastics Scattering Nucleation Nanoparticle Polyethylene Condensed Matter Physics Light scattering law.invention Low-density polyethylene chemistry.chemical_compound chemistry Chemical engineering law Titanium dioxide Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Crystallization |
| Zdroj: | Journal of Polymer Science Part B: Polymer Physics. 44:1084-1095 |
| ISSN: | 1099-0488 0887-6266 |
| DOI: | 10.1002/polb.20763 |
| Popis: | Small-angle light scattering (SALS) measurements were used to study the structure of titanium dioxide (TiO2)/low-density polyethylene (LDPE) nanocomposites. The results showed that the scattering from LDPE crystalline structures and the scattering from TiO2 nanoparticles can be resolved and separated. It is shown that the independent effects of crystallization conditions and the presence of nanoparticle aggregates on the spherulitic structure of the LDPE matrix can be determined by analyzing the scattering patterns using the methods proposed. From the SALS results, we conclude that the nanoparticle surface chemistry affects both nucleation of spherulites and their structure particularly under rapid cooling conditions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1084–1095, 2006 |
| Databáze: | OpenAIRE |
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