Formation and Reactivity of the [Cp‘2Ta(H)2]+ Cation (Cp‘ = η5-tBuC5H4)

Autor:	Claude Moïse, Philippe Sauvageot, Bernd Nuber, André Sadorge, Jean-Claude Leblanc, Marek M. Kubicki
Rok vydání:	1999
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Organic Chemistry Trifluoroacetic acid Reactivity (chemistry) Physical and Theoretical Chemistry Medicinal chemistry
Zdroj:	Organometallics. 18:2133-2138
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om9809973
Popis:	The complex Cp‘2Ta(H)(OCOCF3)2 (2) is synthesized by the acidolysis of Cp‘2TaH3 (1) (Cp‘ = η5-tBuC5H4) in the presence of an excess of trifluoroacetic acid. 1 undergoes a loss of H- upon the reacti...
Databáze:	OpenAIRE
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