A useful approach toward the synthesis and metal extractions with polymer appended thioalkyl calix[4]arenes

Autor:	Shahabuddin Memon, D. Max Roundhill, Mustafa Tabakci, Mustafa Yilmaz
Rok vydání:	2005
Předmět:	Polymers and Plastics Organic Chemistry Extraction (chemistry) Chemical modification Sorption chemistry.chemical_compound Monomer chemistry Liquid–liquid extraction Calixarene Materials Chemistry Nucleophilic substitution Organic chemistry Ion-exchange resin
Zdroj:	Polymer. 46:1553-1560
ISSN:	0032-3861
DOI:	10.1016/j.polymer.2004.12.019
Popis:	This article describes a convenient method for the synthesis of two new polymeric resins via nucleophilic substitution reactions involving 5,11,17,23-tetrakis[(propylthio)methyl]-25,26,27,28-tetrahydroxycalix[4]arene 4 , and 5,11,17,23-tetrakis[(methylthio)methyl]-25,26,27,28-tetrahydroxycalix[4]arene 6 , as precursors with Merrifield's resin. The extraction studies were made using both liquid–liquid extraction and solid–liquid batchwise sorption procedures. The calix[4]arene based polymeric resins have high extraction ability toward metal cations and Na 2 Cr 2 O 7 as compared to their monomeric precursors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c1b6ab44c417997e4e6f251bfc41a085 https://doi.org/10.1016/j.polymer.2004.12.019 Zobrazit plný text záznamu Full Text from ScienceDirect