Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–
| Autor: | A. L. Gushchin, Maxim N. Sokolov, Pavel A. Abramov, I. Kh. Rizvanov, D. V. Stass, Vasily M. Babaev, Vladimir S. Korenev |
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| Rok vydání: | 2019 |
| Předmět: |
Chemistry
Materials Science (miscellaneous) Potassium chemistry.chemical_element Uranium Uranyl Electrochemistry Inorganic Chemistry chemistry.chemical_compound symbols.namesake Uranyl nitrate Polyoxometalate symbols Physical and Theoretical Chemistry Luminescence Raman spectroscopy Nuclear chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 64:1105-1114 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated. |
| Databáze: | OpenAIRE |
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