Réactions D'amines Germaniées avec les Aldéhydes et les Cétones

Autor:	M. Riviere‐Baudet, J. Satgé
Rok vydání:	2010
Předmět:	Dichlorocarbene chemistry.chemical_compound chemistry Hexachloroacetone Germane Imine Organic chemistry Chloral Carbonyl derivatives General Chemistry Medicinal chemistry Decomposition Enamine
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 89:1281-1296
ISSN:	0165-0513
DOI:	10.1002/recl.19700891209
Popis:	The insertion of aldehydes and ketones onto the germanium-nitrogen bond of trialkylgermylamines leads to α-aminoalkoxygermanes which are generally not very stable. Their decomposition leads to trialkylgermanium oxides and enamines or imines corresponding to the aminogermanes and carbonyl derivatives. The formation of enamine or imine takes place through gem-diamines which are usually unstable. The derivatives obtained by insertion of the halogenated aldehydes and ketones such as chloral and hexachloroacetone decompose through β-elimination, with formation of trialkyl(trichloromethyl)germane R3GeCCl3, trialkylchlorogermane and dichlorocarbene.
Databáze:	OpenAIRE
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