Resonance Raman spectra of p-hydroxyazobenzene and its ring-deuterated derivatives

Autor:	Katsunosuke Machida, Yutaka Saito, Hohi Lee, Toyozo Uno
Rok vydání:	1976
Předmět:	chemistry.chemical_classification Crystallography symbols.namesake chemistry Deuterium General Engineering Analytical chemistry symbols Hydrazone Raman spectroscopy Dissociation (chemistry)
Zdroj:	Spectrochimica Acta Part A: Molecular Spectroscopy. 32:1319-1322
ISSN:	0584-8539
Popis:	Resonance Raman spectra of p -hydroxyazobenzene, HO( p )C 6 H 4 NNC 6 H 5 , and its three ring-deuterated derivatives containing ( p )C 6 D 4 and/or C 6 D 5 have been recorded in the neutral and the alkaline pH regions. Based on the observed isotopic frequency shifts, the bands due to the p -disubstituted and monosubstituted rings have been distinguished clearly from each other. The spectral change on alkalifying the neutral solution shows that the contribution of the hydrazone structure in the resonance hybridization increases on the dissociation of a proton from the hydroxyl group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c17442fb918a6a3a98f078f160cfd494 https://doi.org/10.1016/0584-8539(76)80172-9 Zobrazit plný text záznamu