Gas-phase ion-molecule reactions in the C6H6Cr(CO)3 ? NH3 system
Autor: | Yu. S. Nekrasov, V. I. Losilkina, D. B. Zagorevskii, V. A. Piven |
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Rok vydání: | 1987 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:607-609 |
ISSN: | 1573-9171 0568-5230 |
Popis: | 1. Ammoniate ions CrNH3+, Cr(NH3)2+ and C6H6CrNH3+ are formed upon the electron bombardment of a mixture of benzenechromium tricarbonyl and ammonia vapors. 2. The formation of the C6H6CrNH3+ ion in this system is possible only from carbonyl-containing ions, while Cr+and C6H6Cr(CO)3+ ions are inert relative to ammonia. |
Databáze: | OpenAIRE |
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