Gas-phase ion-molecule reactions in the C6H6Cr(CO)3 ? NH3 system

Autor: Yu. S. Nekrasov, V. I. Losilkina, D. B. Zagorevskii, V. A. Piven
Rok vydání: 1987
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:607-609
ISSN: 1573-9171
0568-5230
Popis: 1. Ammoniate ions CrNH3+, Cr(NH3)2+ and C6H6CrNH3+ are formed upon the electron bombardment of a mixture of benzenechromium tricarbonyl and ammonia vapors. 2. The formation of the C6H6CrNH3+ ion in this system is possible only from carbonyl-containing ions, while Cr+and C6H6Cr(CO)3+ ions are inert relative to ammonia.
Databáze: OpenAIRE