Organophotoredox/palladium dual catalytic decarboxylative Csp3–Csp3coupling of carboxylic acids and π-electrophiles

Autor:	Kaitie C. Cartwright, Jon A. Tunge
Rok vydání:	2020
Předmět:	Reaction mechanism Coupling (computer programming) Chemistry Electrophile chemistry.chemical_element Reactivity (chemistry) General Chemistry Combinatorial chemistry Dual (category theory) Catalysis Palladium
Zdroj:	Chemical Science. 11:8167-8175
ISSN:	2041-6539 2041-6520
DOI:	10.1039/d0sc02609c
Popis:	A dual catalytic decarboxylative allylation and benzylation method for the construction of new C(sp3)–C(sp3) bonds between readily available carboxylic acids and functionally diverse carbonate electrophiles has been developed. The new process is mild, operationally simple, and has greatly improved upon the efficiency and generality of previous methodology. In addition, new insights into the reaction mechanism have been realized and provide further understanding of the harnessed reactivity.
Databáze:	OpenAIRE
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