C60Hexagonal Solvate Grown from n-Octane: Solid-State Studies

Autor:	Anne Gonthier-Vassal, H. Szwarc, René Céolin, Viatcheslav N. Agafonov, Siro Toscani, M. F. Gardette
Rok vydání:	1997
Předmět:	Crystallography Fullerene Chemistry Hexagonal crystal system General Chemical Engineering Enthalpy Solid-state Sublimation (phase transition) Desolvation Volume excess N octane
Zdroj:	Fullerene Science and Technology. 5:559-565
ISSN:	1064-122X
Popis:	By slowly evaporating at room temperature solutions of C60 in n-octane, crystals of the hexagonal solvate C60 1 n-octane have been obtained (a = 10.10, c = 10.18 A)., Although these crystals are formed with a negative volume excess of − 24 A3 per formula-unit, their desolvation enthalpy, 60 J g−1 (50 kJ mol−1), is close to the sublimation enthalpy of pure n-octane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c15e334f6ce247efd1139a0c277e485d https://doi.org/10.1080/15363839708015908 Zobrazit plný text záznamu