UV-curable flame-retardant coatings based on phosphorous and silicon containing oligomers
Autor: | Kunal Wazarkar, Durva Naik, Anagha Sabnis |
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Rok vydání: | 2018 |
Předmět: |
Materials science
Silicon chemistry.chemical_element 02 engineering and technology Surfaces and Interfaces General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Epoxy acrylate 0104 chemical sciences Surfaces Coatings and Films Limiting oxygen index Colloid and Surface Chemistry Chemical engineering chemistry Halogen Proton NMR Fourier transform infrared spectroscopy 0210 nano-technology Fire retardant |
Zdroj: | Journal of Coatings Technology and Research. 16:733-743 |
ISSN: | 1935-3804 1547-0091 |
Popis: | Current research on flame-retardant coatings explores alternatives to halogen-based products. Reactive compounds based on phosphorous and silicon were synthesized and cooperated in epoxy acrylate oligomers to form UV-curable flame-retardant wood coatings. FTIR, 1H NMR, hydroxyl and iodine values confirmed successful synthesis of these products. The effect of the varying proportion of the synthesized compounds on the mechanical, chemical and thermal properties of photopolymerized coatings was investigated. Further, the efficacy of flame retardants was estimated by limiting oxygen index and UL-94 vertical burning test. The synergistic behavior between silicon and phosphorous resulted in an optimum formulation giving an LOI of 24 and VTM-0. |
Databáze: | OpenAIRE |
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