Generation of isoquinolino-o-quinodimethanes from fused 3-sulfolenes

Autor:	Hong-Chuan Chen, Ta-Shue Chou
Rok vydání:	1998
Předmět:	Chemistry Organic Chemistry Drug Discovery Organic chemistry Regioselectivity Biochemistry Pyrolysis
Zdroj:	Tetrahedron. 54:12609-12622
ISSN:	0040-4020
Popis:	Isoquinolino-3-sulfolene 7 has been prepared efficiently from 3,4-epoxysulfolene 8 . Deprotonation-alkylation reactions proceed smoothly but with low regioselectivity to give substituted isoquinolino-3-sulfolenes. The pyrolysis of these fused 3-sulfolenes at various temperatures provides an easy entry to the corresponding isoquinolino- o -quinodimethanes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c12c422507002bc468187fd2808165d5 https://doi.org/10.1016/s0040-4020(98)00739-x Zobrazit plný text záznamu Full Text from ScienceDirect